میکانیکیة وحرکیة وثرموداینمیکیة انتقال ایونات حامض الستریک لإزالته بعملیة الامتزاز باستعمال التوصیلیة الکهربائیة وفرق الجهد والدالة الحامضیة
الملخص
استعملت فی هذا البحث ولأول مرة قیم التوصیلیة الکهربائیة وفرق الجهد والدالة الحامضیة واحتمالیة الالتصاق على السطح للکشف عن میکانیکیة انتقال ایونات حامض الستریک بعملیة الامتزاز من طبقة المحلول إلى سطح الصلب باستعمال مادة مازة جدیدة, تم تطبیق النماذج الحرکیة للامتزاز( رتبة اولى وثانیة کاذبة وحرکیة الیوفیج والانتشار الدقائقی الضمنی) على النتائج العملیة للامتزاز فضلا عن ایزوثیرمی فرندلخ وتیمکن, اظهرت هذه الدراسة انتقالیة عالیة لهذا الحامض لتکوین معقد السطح عند التراکیز المخففة ودرجات حراریة منخفضة وانطباقها على حرکیة الرتبة الاولى الکاذبة وحصول انتشار دقائقی ضمنی مسیطر علیه لهذه الایونات واستعمل ثابت فرندلخ وتیمکن للحصول على الدوال الثرموداینمیکیة ΔG,ΔH,ΔS لعملیة الامتزاز.
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